Polyamide makes its mark in high-pressure hydrogen tank for Toyota fuel cell vehicle

PA 6 material is used in blowmolding process

When it comes to hydrogen fuel tanks, HDPE has met its match. The process used by Toyota to manufacture the tank for its Mirai fuel cell vehicle (FCV) entails blowmolding the liner, followed by wrapping with carbon fiber and then impregnating the fiber with epoxy resin that cures at 150°C. Coupled with the requirement that the tank retain its integrity down to a chilling -70°C, Ubenylon 1218IU, a polyamide (PA) 6 material from Ube Industries, was selected as the material of choice.

Toyota’s Mirai FCV employs two hydrogen fuel tanks, made from a PA 6 liner wrapped in a carbon fiber epoxy composite. Each tank can hold 5 kg of hydrogen.

The PA 6 resin reportedly delivers superior performance for hydrogen permeation prevention (an order of magnitude superior to HDPE) and excellent mechanical performance, in terms of durability to withstand sudden changes in tank temperature from filling and discharging hydrogen, and shock resistance in extreme cold.

“Blowmolding was preferred over injection molding due to its superior productivity,” says Masayoshi Baba, Manager, Injection and Composite Technology Group (Polyamide), at Ube’s Polymers Development Center in Ube City, Japan. “The welding step required for injection molded tanks becomes irrelevant.” Wall thickness can also reportedly be controlled with high precision in the blowmolding process. Baba was speaking to PlasticsToday at the recent Chinaplas show in Shanghai.

Prototype tanks for Toyota’s FCV were made of steel, whereas Honda uses aluminum in the tank of its Clarity FCV. The Toyota Mirai uses two fuel tanks. Ube plans to establish a global supply framework for 1218IU to be used as a liner material for high-pressure hydrogen tanks.

Japan’s strategic roadmap targets about 40,000 FCVs on its roads by 2020, about 200,000 by 2025 and about 800,000 vehicles by 2030. These will be served by a hydrogen filling station network of about 160 stations by 2020 and about 320 stations by 2025.

South Korea, meanwhile, targets 700,000 FVCs by 2030. The Hyundai Intrado concept car took pride of place at the Lotte Chemical Chinaplas booth. The monocoque chassis of the fuel cell vehicle features extensive use of carbon-fiber-reinforced plastic composites supplied by the Korean firm. Composite tanks located at the rear of the vehicle, meanwhile, store more than 100 liters of hydrogen pressurized to 700 bar.

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